Highly Enantioselective Hydrosilylation of Ketones Catalyzed by a Chiral Oxazaborolidinium Ion

Byung Chul Kang,Sung Ho Shin,Jaesook Yun,Do Hyun Ryu

Organic Letters（2017）

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摘要

A highly enantioselective hydrosilylation of ketones was developed for the synthesis of a variety of chiral secondary alcohols. In the presence of a chiral oxazaborolidinium ion (COBI) catalyst, the reaction proceeded with good yields (up to 99%) with excellent enantioselectivities (up to 99% ee).

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enantioselective hydrosilylation,ketones catalyzed,chiral oxazaborolidinium hydrosilylation

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