Reactivity of a stable copper-dioxygen complex.
CHEMICAL COMMUNICATIONS(2017)
摘要
We report the isolation of a roomtemperature stable dipyrromethene Cu(O-2) complex featuring a side-on O-2 coordination. Reactivity studies highlight the unique ability of the dioxygen adduct for both hydrogen-atom abstraction and acid/base chemistry towards phenols, demonstrating that side-on superoxide species can be reactive entities.
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关键词
stable copper–dioxygen,reactivity
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