Bimetallic MOFs (H 3 O) x [Cu(MF 6 )(pyrazine) 2 ]·(4 - x)H 2 O (M = V 4+ , x = 0; M = Ga 3+ , x = 1): co-existence of ordered and disordered quantum spins in the V 4+ system.

Jamie L Manson,John A Schlueter,Kerry E Garrett,Paul A Goddard, Tom Lancaster,Johannes S Möller,Stephen J Blundell,Andrew J Steele,Isabel Franke,Francis L Pratt,John Singleton,Jesper Bendix,Saul H Lapidus,Marc Uhlarz,Oscar Ayala-Valenzuela,Ross D McDonald,Mary Gurak,Christopher Baines

CHEMICAL COMMUNICATIONS（2016）

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摘要

The title compounds are bimetallic MOFs containing [Cu(pyz)(2)](2+) square lattices linked by MF6n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.

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