Structure And Electrochemical Performance Of Cu And Al Codoped Nanometer Alpha-Nickel Hydroxide

ADVANCED MECHANICAL DESIGN, PTS 1-3(2012)

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摘要
Nanometer alpha-nickel hydroxide codoped with Cu and Al has been synthesized by the ultrasonic-assisted precipitation method. The crystal structure and particle size were analyzed by X-ray diffraction (XRD) and particle size distribution (PSD). The electrochemical performance of the samples was characterized by the charge/discharge test and cyclic voltammetry. The results of electrochemical tests demonstrated that the specific discharge capacity of Cu/Al codoped alpha-nickel hydroxide (330 mAh/g) is much higher than that of pure spherical nickel (240 mAh/g), and it exhibits a relatively good electrochemical reaction reversibility and large proton diffusion coefficient.
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关键词
Nanometer alpha-nickel hydroxide, Ultrasonic-assisted precipitation, Cu/Al codoped, Electrochemical performance
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