Thermodynamic properties of microporous materials for two copper borates, MCuB 7 O 12 ·H 2 O (M=Na,K)

Huihui Zhang,Na Kong,Jie Wang,Zhihong Liu

The Journal of Chemical Thermodynamics（2015）

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摘要

•Two copper borates MCuB7O12·H2O (M=Na,K) have been synthesised and characterized.•Enthalpies of solution of both copper borates were measured by microcalorimeter.•Enthalpies of solution of CuCl2·2H2O (s) were also measured by microcalorimeter.•ΔfHme for both copper borates were obtained by thermochemical cycles.•KCuB7O12·H2O is more thermal stable than that of NaCuB7O12·H2O.

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关键词

Copper borates,Microporous materials,Standard molar enthalpy of formation,Solution calorimetry

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