Sodium perborate/trifluoroacetic anhydride oxidation of ketones using poly(iodostyrene) as the catalyst: a direct route to alpha-hydroxy ketones

Journal of Chemical Research-s（2014）

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摘要

Exposure of ketones to NaBO3.4H2O/(CF3CO)(2)O in the presence of a catalytic amount of poly(iodostyrene) afforded alpha-hydroxy ketones in good yield, with potential applications in the construction of alpha-hydroxy ketone subunit in natural product synthesis.

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关键词

sodium perborate tetrahydrate,hydroxylation,poly(iodostyrene),alpha-hydroxyketones,(CF3CO)(2)O

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