Lithium and potassium aminoalkoxides

Samuel D Cosham,Andrew L Johnson,Laura Jordan,Mary F Mahon,Kieran C Molloy

MAIN GROUP METAL CHEMISTRY（2012）

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摘要

The structures of the Group 1 metal aminoalkoxides Li[OCH(CH2CNMe2)(2)] (1) and K[OCH(CH2CNMe2)(2)]center dot H OCH(CH2CNMe2)(2) (2) have been determined. 1 is a hexameric drum in which two Li3O3 rings are joined co-facially, whereas 2 is tetrameric and adopts a K4O4 ladder structure, novel for homoleptic potassium alkoxides.

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关键词

aminoalkoxide,lithium,potassium,X-ray

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