Facile Synthesis of a 20‐Membered Macrocyclic Magnesium Sulfide Complex

Wingpor Leung,Yukchi Chan,Thomas C W Mak

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY（2014）

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摘要

Deprotonation of 2,3-pyrazyl-linked bis(thiophosphorano)methane {CH2(iPr(2)P=S)}(2)(C4H2N2-2,3) (2) with one equivalent of nBu(2)Mg in THF afforded a 20-membered macrocyclic magnesium complex [Mg{CH(iPr(2)P-S)}(2)(C4H2N2-2,3)](4) (4a). The structure of 4a has been characterized by X-ray crystallography and NMR spectroscopy.

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关键词

Macrocycles,Supramolecular chemistry,Magnesium,Alkaline earth metals,Self-assembly

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