Hydronium Copper(II)‐tris(5‐nitrotetrazolate) Trihydrate – A Primary Explosive

Mariusz Krawiec,Stephen R Anderson,Pascal Dube,David D Ford,Jerry S Salan,Shannon Lenahan,Neha Mehta, Clifton R Hamilton

PROPELLANTS EXPLOSIVES PYROTECHNICS（2015）

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摘要

The long-time elusive structure of the acid copper(II) salt intermediate in the production of DBX-1 is presented. The single-crystal X-ray shows infinite chains of copper(II) ions complexed by six 5-nitrotetrazolate anions are aligned along the sixfold axis. Hydronium ions are located on the threefold axis with additional neutral water molecules.

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关键词

DBX-1,Energetic metal-organic framework,Primary explosive,NaNT

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