Production of hydrogenated methyl esters of palm kernel and sunflower oils by employing rhodium and ruthenium catalytic complexes of hydrolysis stable monodentate sulfonated triphenylphosphite ligands
Applied Catalysis B: Environmental(2014)
摘要
•Hydrogenation of methyl esters of palm kernel and sunflower oils.•Rh and Ru sulfonated triphenylphosphite complexes.•Superior selectivities compared to triphenylphosphite or triphenylphosphine complexes.•Recovery of metal sulfonated triphenylphosphite catalysts by means of a membrane.•Reactions related to the manufacture of surfactants and foodstuffs with zero amounts of trans-fats.
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关键词
Hydrogenation,Methyl esters of palm kernel and sunflower oils,Rhodium,Sulfonated phosphites,Zero trans-fats
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