Ionic liquid-induced synthesis of a graphene intercalated ferrocene nanocatalyst and its environmental application

Sanjiv Sonkaria,Hyungtae Kim,Sungyong Kim,N Kumari,Young Gyu Kim,Varsha Khare,Sunghoon Ahn

Applied Catalysis B: Environmental（2016）

引用 13|浏览8

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摘要

•Atomic scale structural-chemical templating of reduced graphene oxide (rGO) sheets.•Ionic liquid driven chemical ordering of rGO to a wet defect-rich mesoporous rGO.•rGO-FeOCl self‐assembly assisting stabilization of pentagonal defect geometries.•Intercalation of graphitic ferrocene via the ionothermal decomposition of rGO-FeOCl.•Ferrocene–ferrocenium nanocatalytic redox center facilitating e-mediated reduction.

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关键词

Ferrocene,Ionic liquid,Reduced graphene oxide,Hexavalent Cr,Redox activity

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