Strong blue absorption of green Zn 2 SiO 4 :Mn 2+ phosphor by doping heavy Mn 2+ concentrations

Chemical Physics Letters(2015)

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摘要
•Heavily-doped Zn2SiO4:Mn2+ phosphors with a strong PL under 422nm excitation.•The relaxation of the selection rule on the forbidden intra-transition caused by the increment of Mn–O orbital intermixing.•The solid solubility limit of Mn2+ in Zn2SiO4 host was measured as 9mol%.
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