The synthesis of P 1 -[11-(anthracen-9-ylmethoxy)undecyl]- P 2 -(2-acetamido-2-deoxy-α-D-glucopyranosyl) diphosphate and the study of its acceptor properties in the enzymatic reaction catalyzed by a D-rhamnosyltransferase from Pseudomonas aeruginosa

A. N. Vinnikova, V. I. Torgov,N. S. Utkina, V. V. Veselovsky, T. N. Druzhinina,S. Wang,I. Brockhausen, L. L. Danilov

Russian Journal of Bioorganic Chemistry(2015)

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摘要
P 1 -[11-(anthracen-9-ylmethoxy)undecyl]- P 2 -(2-acetamido-2-deoxy-α-D-glucopyranosyl) diphosphate, a fluorescent derivative of undecyl diphosphate 2-acetamido-2-deoxyglucose, was chemically synthesized. The ability of the compound to serve as acceptor substrate for the transfer of D-rhamnose residue by D-rhamnosyltransferase WbpZ from Pseudomonas aeruginosa PAO1 was demonstrated.
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P1-[11-(anthracen-9-ylmethoxy)undecyl]-P2-(2-acetamido-2-deoxy-α-D-glucopyranosyl) diphosphate, fluorescent substrate, D-rhamnosyltransferase, Pseudomonas aeruginosa PAO1
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