Structural studies of copper(II) complexes derived from di-2-pyridyl-ketone, (py)2CO

Rebecca L Melen,Jeremy M Rawson,Dana J Eisler

Polyhedron（2012）

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摘要

Reaction of ligand L with CuCl2·2H2O in DMF unexpectedly yielded the tetranuclear complex 1 via metal-catalysed hydrolysis of both DMF and ligand L. Notably 1 was not readily obtained from CuCl2·2H2O and dipyridylketone in DMF, instead forming monmeric and polymeric copper complexes.

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关键词

Thiazyl ligand,Dipyridylketone,Dipyridyldihydroxymethane,Copper complexes

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