Pressure dependent magnetic behavior of 1D ferrimagnetic meso -tetrakis((4-chlorophenyl)porphyrinato)manganese(III) tetracyanoethenide, [Mn III TClPP] + [TCNE] −

Polyhedron(2014)

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摘要
The magnetic ordering temperature, Tc, reversibly increases by 50% between ambient pressure and 7.51kbar for [MnTClPP][TCNE] {MnTClPP=meso-tetrakis((4-chlorophenyl)porphyrinato)-manganese(III)]; TCNE=tetracyanoethylene}. This continuous increase differs from that reported for related compounds.
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关键词
Organic-based magnet,Magnetization,Pressure,Metalloporphyrin,Manganese
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