Investigation of a spiro to ansa rearrangement with di-functional alcohols in cyclotriphosphazene derivatives

Serap Beşli,Simon J. Coles, L. Susanne Coles,David B. Davies,Adem Kılıç

Polyhedron（2012）

引用 18|浏览8

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摘要

Reactions of cyclotriphosphazene derivatives having five-membered spiro rings, N3P3Cl4[O(CH2)2X] (X=NH or O) with the sodium salts of 1,3-propanediol give rearrangements to form stable seven-membered ring ansa compounds, even though crystallographic evidence shows distortion and compression of the cyclophosphazene ring.

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关键词

Cyclotriphosphazenes,Molecular rearrangement,Crystal structures,N3P3 ring distortions,Mechanism

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