Water-induced dynamic crystal-to-amorphous transformation of cobalt(II) coordination and supramolecular frameworks containing benzene-1,2,4,5-tetracarboxylic acid and trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene ligands

Jureepan Piromchom,Jaursup Boonmak,Kittipong Chainok,Sujittra Youngme

Polyhedron（2015）

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摘要

The crystal structures of two Co(II) metal–organic frameworks, a 3D network and a dinuclear molecule have been characterized. Interestingly, the property of the water-induced reversible crystal-to-amorphous transformation with chromotropism is observed for both distinct compounds.

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关键词

Cobalt(II) coordination and supramolecular framework,Trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene,Benzene-1,2,4,5-tetracarboxylic acid,Chromotropism,Dynamic structural transformation

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