Zn(II) and Co(III) metallosupramolecular assemblies derived from a rigid bis-Schiff base ligand

E Liu,Yuan Zhuo Zhang,Jiawen Tan,Chengxiong Yang,Li Li,James A. Golen,Arnold L. Rheingold,Guoqi Zhang

Polyhedron（2015）

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摘要

Diverse Zn(II) and Co(III) supramolecular assemblies were revealed through the introduction of a rigid bis-Schiff base ligand. X-ray structural analysis confirmed the formation of three novel metal–organic architectures including pentanuclear discrete zinc(II) cluster complex, 1-D coordination polymeric chain and dinuclear triple-stranded cobalt(III) helicate by slightly altering the reaction conditions.

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关键词

Schiff base,Zinc(II),Cobalt(III),Self-assembly,Photoluminescence

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