Synthesis, theoretical calculations and antimicrobial studies of copper(I) complexes of cysteamine, cysteine and 2-mercaptonicotinic acid

Saeed Ahmad,Arturo Espinosa,Tayyaba Ahmad,Manzar Sohail,Anvarhusein A. Isab,Muhammad Saleem,Abdul Hameed,Muhammad Monim-ul-Mehboob,Édgar de las Heras

Polyhedron（2015）

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摘要

Three new Cu(I)-thiol complexes of cysteamine, cysteine and 2-mercaptonicotinic acid were prepared. According to DFT calculations they show dimeric structures with differently distorted Cu2(μ-X)2 cores (X: Cl, I) and displaying short cuprophilic Cu⋯Cu contacts. An additional thiolate-Cu(I) derivative also shows dimeric structure with two antiparallel linearly arranged N–Cu–S moieties.

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关键词

Copper(I) complexes,Cuprophilicity,Thiols,Theoretical calculations,Antimicrobial activity

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