Reactive perfluoropolyoxyalkylene oligomers. II. Isothermal equilibrium on silica gel: Macromolecular aggregation

Claudio Tonelli,Roberto Valsecchi, Leonid N Mashlyakovsky,Elena Khomko

Journal of Fluorine Chemistry（2015）

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摘要

Apparent irreversibility of the adsorption of bifunctional oligomers and progressive loss of efficiency of the silica gel: over-aggregation inside the pores (“size confinement effect”) and clusters formation at high concentration level (“size exclusion effect”).

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关键词

Perfluoropolyethers,Silica gel,Hydrogen bonding,Aggregation,Size exclusion,Size confinement

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