Microwave-Assisted Heck Arylations of Non-Activated N-Acyl-3-pyrrolines with Arenediazonium Tetrafluoroborates

Fernanda G. Finelli,Marla N. Godoi,Carlos R. D. Correia

Journal of the Brazilian Chemical Society（2015）

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摘要

Successful Heck-Matsuda arylations of non-activated olefins applying microwave irradiation as an alternative heating mode are presented. Cleaner reactions were performed with arenediazonium tetrafluoroborates bearing electron-donating and electron-withdrawing groups in good to excellent yields with reaction times reduced from 3.5-18 h to 12-30 min.

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关键词

microwave-assisted organic synthesis,Heck-Matsuda,non-activated olefins,arenediazonium salts,palladium

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