Strategy for silicon based hot-wire chemical vapor deposition without wire silicide formation

Artur Laukart, Tino Harig,Markus Hofer,Lothar Schafer

Thin Solid Films(2015)

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摘要
Silicide formation of wires during hot-wire chemical vapor deposition (HWCVD) of silicon based coatings is a key challenge which has to be overcome before HWCVD can be transferred successfully into industry. Silicide formation of tungsten wires is not occurring at temperatures of approximately 1900°C and above when maintaining a silane partial pressure below approximately 1Pa. Proceeding silicide formation at the cold ends where the wires are electrically contacted was completely prevented by continuously moving the cold ends of the wires into the hot deposition zone, resulting in a retransformation of the tungsten phase. Thus the maintenance period of a HWCVD manufacturing tool can be freed from wire lifetime.
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关键词
Hot-Wire CVD,Catalytic CVD,Silicide formation,Tungsten wire
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