Enantio- and diastereoselective synthesis of β-substituted-δ-aminoboronic esters from nitriles
Cheminform(2013)
摘要
The first stereocontrolled synthesis of the title δ-aminoboronic esters—proceeding from commercially available nitriles—via a reduction, Brown’s ‘allyl’ boration reaction, a Boc-protection, a hydroboration, an oxidative elimination of α-pinene, and an esterification reaction, has been reported in excellent enantio- and diastereoselectivities.
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关键词
Amino-boronic ester,Allylboration,Crotylboration,Methoxyallylboration,Nitriles
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