ChemInform Abstract: Chemoselective Intramolecular Allylic C—H Amination versus C=C Aziridination Through Co(II)‐Based Metalloradical Catalysis.

Hongjian Lu,Huiling Jiang,Yang Hu,Lukasz Wojtas,X Peter Zhang

Cheminform（2012）

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摘要

Azathiazine derivatives are selectively synthesized by intramolecular allylic C—H amination of both N-bishomoallylic and N-allylic sulfamoyl azides using a Co(II)—porphyrin catalyst.

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