A New Acridine-Imidazolium-Based Cholestane Receptor for Anion Sensing
BULLETIN OF THE KOREAN CHEMICAL SOCIETY(2011)
摘要
A new highly selective receptor (3) based on an acridine-imidazolium functionalized cholestane for anion sensing was designed and synthesized. A binding study of 3 with various anions was assessed by UV-vis and fluorescence spectroscopies in dry CH3CN. Receptor 3 showed the highest selectivity toward hydrogen pyrophosphate (Ka = 1.5 x 10(4) M-1).
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关键词
Fluorescence sensing,Acridine,Imidazolium,Hydrogen pyrophosphate,3,7-Diaminocholestane
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