Asymmetric Autocatalysis Triggered by Chiral Crystal of Achiral Ethylenediamine Sulfate

Arimasa Matsumoto,Takahiro Ide,Yoshiyasu Kaimori,Satoshi Fujiwara,Kenso Soai

CHEMISTRY LETTERS（2015）

引用 25|浏览4

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摘要

Achiral ethylenediamine forms chiral structures spontaneously when crystallized as the sulfate salt. By using these chiral crystals of ethylenediamine sulfate (ethylenediammonium sulfate), asymmetric autocatalysis of pyrimidyl alkanol affords a highly enantioenriched product with chirality that is determined by the chirality of the crystals.

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