Photophysical Properties of CdSe/CdS core/shell quantum dots with tunable surface composition

Chemical Physics(2016)

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摘要
•Surface stoichiometry of CdSe/CdS quantum dots are controlled with chalcogenide precursors.•Anion (cation) terminated surfaces quench (restore) photoluminescence.•Calculations suggests quenching is due to hole surface states.•Time-resolved photoluminescence also reflects surface composition effects.
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关键词
Nanocrystals,Surface chemistry,Nonradiative relaxation,Photoluminescence,Time-resolved,Synthesis
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