Bis(4-aminobenzoato)-κ2O,O′;κO-(2,2′-bipyridine-κ2N,N′)zinc
Acta Crystallographica Section E-structure Reports Online(2011)
摘要
In the title complex, [Zn(C7H6NO2)2(C10H8N2)], the ZnII cation is coordinated by two aminobenzoate anions and one 2,2′-bipyridine ligand in a distorted trigonal–bipyramidal geometry. The carboxylate group of one aminobenzoate anion coordinates to the ZnII cation in a monodentate manner, whereas the carboxylate group of the other aminobenzoate anion chelates the Zn cation with different Zn—O bond lengths. Intermolecular N—H⋯N and N—H⋯O hydrogen bonding is present in the crystal structure.
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关键词
bis4-aminobenzoato-κ<sup>2</sup><i>o</i><i>o</i>′,κ<i>o</i>-22′-bipyridine-κ<sup>2</sup><i>n</i><i>n</i>′zinc,bis4-aminobenzoato-κ<sup>2</sup><i>o</i><i>o</i>′,κ<i>o</i>-22′-bipyridine-κ<sup>2</sup><i>n</i><i>n</i>′zinc
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