Breaking bonds with mid IR pulses: Femtosecond photolysis of gas-phase metal carbonyls

Lars Windhorn,Thomas Witte,Jake S Yeston,D Proch,Marcus Motzkus,Karlludwig Kompa,Werner Fus

Springer Series in Chemical Physics（2003）

引用 23|浏览1

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摘要

Resonant infrared multiphoton dissociation of Cr(CO)(6), Mo(CO)(6), W(CO)(6), Fe(CO)(5), and Ni(CO)(4) was effected by mid IR femtosecond laser pulses. This requires an excitation to at least v = 7 or 8 of the CO stretch vibration.

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