Carbene Catalysis: Beyond the Benzoin and Stetter Reactions
Topics in Organometallic Chemistry（2013）
摘要
The discovery and development of new N-heterocyclic carbene-catalyzed reaction is described. Based on inspiration from nature, we have taken thiazolium-based approaches to umpolung reactivity and invented a suite of related reactions involving acyl anions, homoenolate, and enolate nucleophiles all generated under catalytic conditions.
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关键词
Asymmetric methodology,Biomimetic,Catalysis,Lewis base,Umpolung
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