Random Packing of Small Blocks: Pressure Effects, Orientational Correlations and Application to Polymer-Based Composites

Packing is a complex phenomenon of prominence in many natural and industrial processes (liquid crystals, granular materials, infiltration, melting, flow, sintering, segregation, sedimentation, compaction, etc.). A variety of computational methods is available in particular for spheroid particles. Our aim is to apply the principle of the random sequential addition algorithm but with small blocks of varying size and orientation. Here the main purpose is to reproduce the observed arrangement of graphitic assemblies in polymeric matrices. Random packing is improved by applying an external pressure implemented with a drifted diffusive motion of the fillers. Attention is also paid to the emergence of structural and orientational order. Interestingly, mixtures of fillers of irregular shapes can be dealt with efficiently using the proposed algorithm.