Reevaluation of matrix-isolation infrared spectra of the isotopologues of trans -diazene and attempts to prepare cis -diazene by photoisomerization

Norman C Craig, Kwabena J Appiah,Charles E Miller,Michael V Seiden, Joseph E Varley

Journal of Molecular Spectroscopy（2015）

引用 4|浏览17

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摘要

•Matrix-isolation IR spectra for trans-diazene-d0, -d1, and -d2.•Definitive assignments of vibrational fundamentals of all three H/D species.•Improved method for synthesizing pure trans-diazene.•Attempt to photoisomerize the trans isomer into the cis isomer.

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关键词

Cis- and trans-diazene,Infrared,Matrix isolation,Calculated infrared intensities

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