Solvent-regulated assemblies and guest-adsorption properties of Ag(I) coordination polymers with p -phenylenediacetonitrile

xiang liu
xiang liu
ningxia xu
ningxia xu

Inorganica Chimica Acta, pp. 124-133, 2015.

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Keywords:
p-PhenylenediacetonitrileSilver(I) complexSolvent effectGuest adsorption

Abstract:

Three unique Ag(I) complexes based on p-phenylenediacetonitrile were synthesized by regulation of solvents system. Crystallization from benzene and m-xylene yielded two distinct 2D layered frameworks 1 and 2, respectively. Recrystallization of guest-eliminated 1a from DMSO produced 3 with different structure from 1a yet same chemical form...More

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