[Li 2 {CH 2 S(O)Ph} 2 (TMEDA) 2 ] – An α-sulfinyl-functionalized methyllithium carbenoid

Gerd Ludwig,Dieter Strohl,Harry Schmidt,Dirk Steinborn

Inorganica Chimica Acta（2015）

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摘要

The aggregation state of the α-sulfinyl-functionalized methyllithium compound [Li2{CH2S(O)Ph}2(TMEDA)2] in solution and its carbenoid reactivity is presented.

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关键词

Lithiated sulfoxides,Carbenoid reactivity,Aggregation state,DOSY NMR measurements

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