Thermal evolution of the morphology of Ni/Ge(111)-c(2 × 8) surface

The thermal evolution of the interface formed by room temperature (RT) deposition of Ni atoms (coverage 0.1, 0.5, 1.2 ML) onto a Ge(111)-c(2 × 8) surface has been studied with the use of scanning tunneling microscopy (STM). Atomically resolved STM images revealed that, at RT, the boundaries between the different c(2 × 8) domains acted as nucleation sites for Ni atoms. After annealing the surface with deposited material at 473 to 673 K the formation of nano-sized islands of Ni x Ge y compounds was observed. In addition, the occurrence of ring-like structures was recorded. Based on the dual-polarity images the latter were assigned to Ni atoms adsorbed on Ge adatoms.