Oxidation and nitration of mononitrophenols by a DyP-type peroxidase.

Enrico Büttner,René Ullrich,Eric Strittmatter,Klaus Piontek,Dietmar A Plattner,Martin Hofrichter,Christiane Liers

Archives of Biochemistry and Biophysics（2015）

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摘要

•Nitrophenol oxidation further demonstrates the high-redox potential character of DyPs.•Major reaction products were dinitrophenols, quinones and polymers.•AauDyP-driven nitration occurs via nitrophenol (transnitration) or NaNO2.•By molecular docking a potential binding pocket for pNP in AauDyP were found.

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关键词

Dye-decolorizing peroxidases,Nitration,Nitrophenol,Nitrite,One-electron oxidation

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