Photoinduced electron transfer between 2-methylanthraquinone and triethylamine in an ionic liquid: time-resolved EPR and transient absorption spectroscopy study.

Guanglai Zhu,Yu Wang,Haiying Fu,Xinsheng Xu,Zhifeng Cui,Xuehan Ji,Guozhong Wu

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy（2015）

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摘要

•TR-EPR and transient absorption spectra of MeAQ− in [bmim][PF6] were recorded.•CIDEP signal was changed to net absorption at longer delay times in [bmim][PF6].•Lifetime of transient radical in [bmim][PF6] was longer than that in acetonitrile.•Various factors have an influence on photoinduced electron transfer in [bmim][PF6].

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关键词

1-Butyl-3-methylimidazolium hexafluorophosphate,Photoinduced electron transfer,Time-resolved electron paramagnetic resonance,Transient absorption spectra,Radical

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