Retraction: Predicting New Ugi-Smiles Couplings: A Combined Experimental and Theoretical Study.
Chemistry (Weinheim an der Bergstrasse, Germany)(2017)
摘要
Following our previous mechanistic studies of multicomponent Ugi-type reactions, theoretical calculations have been performed to predict the efficiency of new substrates in Ugi-Smiles couplings. First, as predicted, 2,4,6-trichlorophenol experimentally gave the corresponding aryl-imidate. Theoretical predictions of nitrosophenols as good acidic partners were then successfully confirmed by experiments. In the latter case, the reaction offers a new access to benzimidazoles.
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