Enantiodifferentiation Through Frequency- Selective Pureshift H-1 Nuclear Magnetic Resonance Spectroscopy

Laura Castanar,Miriam Perez-Trujillo,Pau Nolis,Eva Monteagudo,Albert Virgili,Teodor Parella

CHEMPHYSCHEM（2014）

引用 36|浏览2

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摘要

A frequency-selective 1D H-1 nuclear magnetic resonance (NMR) experiment for the fast and sensitive determination of chemical-shift differences between overlapped resonances is proposed. The resulting fully homodecoupled H-1 NMR resonances appear as resolved 1D singlets without their typical J(HH) coupling constant multiplet structures. The high signal dispersion that is achieved is then exploited in enantiodiscrimination studies by using chiral solvating agents.

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关键词

chemical shift, homodecoupling, enantioselectivity, nmr spectroscopy, single pulsed-field-gradient echo

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