Photo- and thermo-induced spin crossover in a cyanide-bridged {Mo(V)2Fe(II)2} rhombus molecule.

Abhishake Mondal,Yanling Li,Lise-Marie Chamoreau,Mannan Seuleiman,Lionel Rechignat,Azzedine Bousseksou,Marie-Laure Boillot,Rodrigue Lescouëzec

CHEMICAL COMMUNICATIONS（2014）

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摘要

The self-assembly of [Mo-V(CN)(8)](3-) and [Fe-II(bik)(2)(S)(2)](2+) affords a cyanide-bridged {(Mo2Fe2II)-Fe-V} rhombus molecule that shows photo-magnetic effect under laser light irradiation at low temperature and exhibits thermo-induced spin crossover near ambient temperature.

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