Reactive 4a-alkyl-4aH-carbazoles by catalytic dearomatisation, and their unusual dimerisation and dealkylation reactions.

Robin B. Bedford,Craig P. Butts,Mairi F. Haddow,Robert Osborne,Rosalind F. Sankey

CHEMICAL COMMUNICATIONS（2009）

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摘要

Despite their intrinsic instability, 4a-alkyl-4aH-carbazoles can be generated by a catalytic dearomatisation process; their reactivity is demonstrated by facile dealkylation and highly unusual cyclodimerisation processes.

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