An aqueous non-heme Fe(IV)oxo complex with a basic group in the second coordination sphere.

Mads Sørensen Vad,Anders Lennartson,Anne Nielsen,Jeffrey Harmer,John E McGrady,Cathrine Frandsen,Steen Mørup,Christine J McKenzie

CHEMICAL COMMUNICATIONS（2012）

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摘要

The Fe(IV)oxo complex of a coordinatively flexible multidentate mono-carboxylato ligand is obtained by the one electron oxidation of a low spin Fe(III) precursor in water.

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crystal structure

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