Ring-opening dynamics of jadomycin A and B and dalomycin T.

Ray T. Syvitski,Charles N. Borissow,Cathy L. Graham,David L. Jakeman

ORGANIC LETTERS（2006）

引用 34|浏览2

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摘要

A novel oxazolone ring-opening and interconversion process between the two jadomycin diastereomeric forms has been characterized by NMR spectroscopy. An analogue, dalomycin T, has been isolated for the first time and does not undergo interconversion.

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