Iron-mediated C-H coupling of arenes and unactivated terminal alkenes directed by sulfur.

Craig W Cavanagh,Miles H Aukland,Alan Hennessy,David J Procter

CHEMICAL COMMUNICATIONS（2015）

引用 18|浏览8

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摘要

A sulfur-directed Fe(III)-mediated ortho C-H coupling of arenes with unactivated terminal alkenes gives products of regioselective alkene chloroarylation. The novel mechanism involves redox-activation of the arene partner and alkene addition to the resultant aryl radical cation.

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