Derivative multiple reaction monitoring and single herb calibration approach for multiple components quantification of traditional Chinese medicine analogous formulae.
Journal of Chromatography A(2015)
摘要
•Based on MS2 of IT/MS, DeMRM was proposed for direct and rapid transitions design.•SHCA was employed instead of standards to construct the calibration curve.•The method achieved favorable performance for multi-component quantification.•Compatibility-induced alterations in chemicals were investigated methodically.
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关键词
Derivative multiple reaction monitoring,Single herb calibration approach,LC-MS,Analogous formulae,Xiao-Banxia decoction
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