Linh2bh3 Center Dot Nh3bh3: Structure And Hydrogen Storage Properties

Chengzhang Wu,Guotao Wu,Zhitao Xiong,Xiuwen Han,Hailiang Chu,Teng He,Ping Chen

CHEMISTRY OF MATERIALS（2010）

引用 68|浏览3

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摘要

LiNH2BH3 center dot NH3BH3, synthesized by reacting LiH and 2 equiv of NH3BH3 or by reacting equiv LiNH2BH3 and NH3BH3, is composed of alternative LiNH2BH3 and NH3BH3 layers. The compound starts to release hydrogen at 57 degrees C and can desorb ca. 14.0 wt % hydrogen in a stepwise manner with peak temperatures at 80 and 140 degrees C, respectively.

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