Enhancive synthesis of (±)-1β,11-diol-4-en-eudesmol
Chinese Journal of Chemistry(2003)
摘要
An enhancive synthesis of (±)-1β,11-diol-4-en-eudesmol, starting from 2-chloroacrylonitrile, is described. The effect of temperature on the Diels-Alder reaction of 2-chloroacrylonitrile with 2-methylfuran and the condition of cationic cyclization of diene were discussed in detail.
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关键词
Cationic cyclization,Diels-Alder reaction,Eudesmane,Sesquiterpenoids
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