The heterometallic cluster catalyzing coordinative hydrogenation and isomerization promoted by oxygen transfer reagent

The oxygen transfer reagent (OTR), Me3NO . 2H(2)O and PhIO, can promote the coordinative hydrogenation and isomerization of 1-hexane catalyzed by heterometallic carbonyl clusters, SRuCo2(CO)(9) and SeRuCo2(CO)(9), The tetrahedral skeleton of the catalyst keeps intact in catalysis process, In methanol solution, [1-Hexene]/[Cat.]=200, [Me3NO . 2H(2)O]/[Cat.]=4, P-H2=5.0 similar to 6.0 MPa, 60 degrees C and in 24 h are the best conditions, A plausible mechanism is given.