Site specific carboxylation of abnormal anionic N-heterocyclic dicarbenes with CO2.

Monika Vogt,Chao Wu,Allen G Oliver,Christopher J Meyer,William F Schneider,Brandon L Ashfeld

CHEMICAL COMMUNICATIONS（2013）

引用 23|浏览25

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摘要

Herein, we report experimental and computational results for the carboxylation of abnormal anionic N-heterocyclic dicarbenes (NHDCs) with CO2. Under ambient dosing conditions, carbonyl addition occurs selectively at C4 without a second carboxylation event occurring at the C2 carbene center.

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