Spectral, thermal and DFT studies of novel nickel(II) complexes of 2-benzoylpyridine-N4-methyl-3- thiosemicarbazone: Crystal structure of a square planar azido-nickel(II) complex

K. Jayakumar,E. B. Seena,M. R. Prathapachandra Kurup, Savas Kayac,Goncagul Serdaroglu,E. Suresh,Riadh Marzouki

Journal of Molecular Structure（2022）

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摘要

•Nickel(II) complexes of a thiosemicarbazone were synthesized.•Single crystal X-ray analysis one Ni(II) establishes square planar geometry.•IR studies prove the tridentate nature of thiosemicarbazone.•The quantum chemical results explain the reactivity tendency of the compounds.

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关键词

2-Benzoylpyridine,Thiosemicarbazone,Nickel(II) complex,Square planar,X-ray crystallography,NBO analysis

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